There are two bearings in each hub.... and you replace both when you do a hub.
To remove the rear bearing, you need to remove (and therefore want to replace) the "hub oil seal.
Most parts are interchangeable across the axles (Defender, Disco 1, RRC) however the locking washer (that stops the hub-nuts from undoing) has 2 forms.... and if you can't re-use it then you need the right version...